Search results for " Magnetization"
showing 10 items of 37 documents
Interplay between Chemical Composition and Cation Ordering in the Magnetism of Ni/Fe Layered Double Hydroxides
2013
We report the synthesis of a family of ferrimagnetic NiFe layered double hydroxides (LDHs) with a variable Ni(2+)/Fe(3+) in-plane composition of [Ni(1-x)Fe(x)(OH)2](CO3)(x/2)·yH2O (x = 0.20, 0.25, and 0.33) by following a modified homogeneous precipitation. These layered magnets display high crystallinity, homogeneous hexagonal morphologies, and micrometric size that enable their quantitative exfoliation into single layers by sonomechanical treatment of the solids in polar solvents. This was confirmed by dynamic light scattering, UV-vis spectroscopy, high-resolution transmission electron miscroscopy, and atomic force microscopy methodologies to study the resulting steady suspensions. Our ma…
Room Temperature Magnetism in Layered Double Hydroxides due to Magnetic Nanoparticles
2013
Some recent reports claiming room temperature spontaneous magnetization in layered double hydroxides (LDHs) have been published; however, the reported materials cause serious concern as to whether this cooperative magnetic behavior comes from extrinsic sources, such as spinel iron oxide nanoparticles. The syntheses of crystalline Fe(3+)-based LDHs with and without impurities have been developed, highlighting the care that must be taken during the synthetic process in order to avoid misidentification of magnetic LDHs.
A Measurement System for Power Inductors in Non-Linear Operating Conditions
2021
The exploitation of power inductors in switching converters outside the linear region requires detailed information on the magnetization curve that often is not included among those usually available on their datasheets. This paper proposes an automatic system in which the inductor is characterized in real operating conditions taking into account also the core temperature. It is based on a switching converter suitably controlled by a virtual instrument. The system was tested by retrieving the inductance vs current curves of two commercial inductors for core temperatures up to 105°C, showing the different behaviors of the magnetization curves. Results are coherent with data given by manufact…
Pressure induced increase in Tc for the organic-based magnet FeII(TCNE)2 (TCNE=tetracyanoethylene)
2013
Abstract Pressure dependent magnetization and 57Fe Mossbauer studies were performed on Fe(TCNE)[C4(CN)8]1/2·zCH2Cl2 (TCNE = tetracyanoethylene). Pressure did not influence the Mossbauer parameters in paramagnetic state. Mossbauer data reveals the onset of magnetic ordering at 130 K and significant enhancement of the magnetic ordering temperature from 100 to 150 K accompanied by an increase of the spontaneous magnetization, which is higher than reported from the magnetic data, and application of pressure induces the reversible formation of a new, metastable magnetic species. These changes suggest an increase of the dimensionality of magnetic interaction, i.e., stronger interlayer coupling. A…
On/Off Photoswitching in a Cyanide-Bridged {Fe2Co2} Magnetic Molecular Square
2013
International audience; A repeatable bidirectional paramagnetic ↔ diamagnetic photomagnetic effect has been observed in the cyanide-bridged Fe-Co square complex {[Fe{B(pz)(4)}(CN)(3)](2)[Co(bik)(2)](2)}(ClO(4))(2)*3H(2)O [B(pz)(4) = tetrapyrazolylborate, bik = bis(1-methylimidazol-2-yl)ketone]. Magnetic measurements and low-temperature single-crystal X-ray diffraction experiments have shown that a complete electron transfer from the diamagnetic Fe(II)-Co(III) state to the paramagnetic Fe(III)-Co(II) metastable state is induced by 808 nm laser light irradiation, whereas the diamagnetic state is recovered in an almost quantitative yield under irradiation at 532 nm.
Thermal Stability of a DC/DC Converter with Inductor in Partial Saturation
2021
Inductors operated in quasi saturation in dc–dc converters allow reduction of the core size and realization costs; on the other hand, they imply an increase of dissipated power that can jeopardize the thermal stability of the converter. In this article, this issue is studied by a mathematical model able to represent both the inductor nonlinearity and its temperature dependence. The main losses, such as ohmic, skin effect and magnetic, are taken into account in the model. The inductor is characterized by a polynomial curve whose parameters are a function of the temperature. Finally, the whole converter is modeled and simulation results, obtained on a boost converter, are compared with experi…
High precision hyperfine measurements in Bismuth challenge bound-state strong-field QED
2017
Electrons bound in highly charged heavy ions such as hydrogen-like bismuth 209Bi82+ experience electromagnetic fields that are a million times stronger than in light atoms. Measuring the wavelength of light emitted and absorbed by these ions is therefore a sensitive testing ground for quantum electrodynamical (QED) effects and especially the electron–nucleus interaction under such extreme conditions. However, insufficient knowledge of the nuclear structure has prevented a rigorous test of strong-field QED. Here we present a measurement of the so-called specific difference between the hyperfine splittings in hydrogen-like and lithium-like bismuth 209Bi82+,80+ with a precision that is improve…
High field magnetization of the colloidal Mn–Zn ferrite
1999
Abstract The magnetic properties of a hydrocarbon based colloid (stabilized by oleic acid) of polydisperse chemically co-precipitated Mn 0.5 Zn 0.5 Fe 2 O 4 particles are discussed in the paper. Two fractions are separated from an initial ferrofluid sample by centrifugation. X-ray diffraction measurements show the crystal structure of the particles and a broadened shape of the diffraction lines. Mean particle diameters 6.2 nm (the light fraction) and 9.7 nm (the heavy one) were determined by TEM measurements. The magnetization of the colloids is measured by VSM up to 12 T. A significant slope in the magnetization curves in the high field region is displayed for both samples in the temperatu…
{CoIII2DyIII2} single molecule magnet with two resolved thermal activated magnetization relaxation pathways at zero field
2014
The new complex [CoIII2DyIII 2(OMe)2(teaH)2(Piv)6] in the {CoIII2DyIII2} family, shows two well resolved thermal activated magnetization relaxation pathways under AC experiments in zero DC field. Fitted crystal field parameters suggest that the origin of these two pathways relies on two different excited mJ sub-levels. Fil: Funes, Víctor Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina …
A field induced ferromagnetic-like transition below 2.8 K in Li2CuO2: An experimental and theoretical study
1998
The low temperature magnetic properties of the Li2CuO2 compound have been investigated by means of superconducting quantum interference device magnetometry. We find in addition to an antiferromagnetic phase below 9.5 K a ferromagnetic-like steep rise of the magnetization around 2.8 K. The observed low temperature behavior is discussed by considering second and fourth order magnetocrystalline effective anisotropy coefficients, in addition to the exchange couplings reported in the literature. Work at the Institut de Ciencia dels Materials was supported by the Spanish Comisión Interministerial de Ciencia y Technología Grant No. CICYT MAT 96-1037.